HCID 57702307, compound → HCID 57702302, compound

HRID 1952323Notes

Reaction equation

HRID 1952323 reaction equation
[S:1]1[CH:3]([C:4]([CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])=[CH2:5])[CH2:2]1>C1C=CC=CC=1>[CH2:6]([C:4]1[CH2:3][S:1][CH2:2][CH:5]=1)[CH2:7][CH2:8][CH2:9][CH2:10][CH3:11]

Participants

3

Reactant 1

HCID 57702307HCID 57702307, compound

Product 1

HCID 57702302HCID 57702302, compoundYield 95%

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

A solution of 1,2-epithio-3-hexyl-3-butene (40 mg, 0.24 miol) and Cu(hfacac)2 (1.2 mg, 2.4 μmol) in benzene (1 mL) was heated at 100° C. for 1 h in a pressure tube. Concentration of the solvent in vacuo afforded a residue, which was purified by column chromatography (n-pentane) to give 3-Hexyl-2,5-dihydrothiophene (38 mg, 95%) as a colorless oil.

Workup

  1. customConcentration of the solvent in vacuo afforded a residue, which
  2. customwas purified by column chromatography (n-pentane)

Sources & evidence

ORD record
ord-492348bac5e94af988c1c57b84c39d3b
Source dataset
uspto-grants-2013_03
Patent number
US08404872B2

Reaction notes

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