HCID 57702319, compound → HCID 57702317, compound

Participants

Reaction Steps

A solution of 2-cyclohex-1-enyl-thiirane (100 mg, 0.7 mmol) and Cu(tfacac)2 (78 mg, 0.21 mmol) in benzene (21 mL) were heated to 100° C. for 24 h under N2. After cooling, concentration of the solvent in vacuo afforded a residue, which was purified by column chromatography (n-pentane) to give 2,4,5,6,7,7a-Hexahydro-benzo[b]thiophene (35 mg, 35%) as a yellow oil.

Provenance & Evidence