Acetate → 5,6-Dihydro-benzo[f]quinoline

HRID 195233Notes

Reaction equation

[B-:22]([F:23])([F:24])([F:25])[F:26].[Br:1][c:2]1[c:3]([CH2:8][CH2:9][c:10]2[cH:11][cH:12][cH:13][cH:14][cH:15]2)[n:4][cH:5][cH:6][cH:7]1.[CH3:55][N:56]([CH3:57])[C:58](=[O:59])[CH3:60].[CH:27]1([PH+:28]([CH:29]2[CH2:30][CH2:31][CH2:32][CH2:33][CH2:34]2)[CH:35]2[CH2:36][CH2:37][CH2:38][CH2:39][CH2:40]2)[CH2:41][CH2:42][CH2:43][CH2:44][CH2:45]1.[K+:16].[K+:17].[O-:18][C:19]([O-:20])=[O:21].[O-:47][C:48]([CH3:49])=[O:50].[O-:51][C:52]([CH3:53])=[O:54].[Pd+2:46]>>[c:2]12[c:3]([n:4][cH:5][cH:6][cH:7]1)[CH2:8][CH2:9][c:10]1[c:11]-2[cH:12][cH:13][cH:14][cH:15]1

Participants

Reactant 8

HCID 175Acetate2×

HCID 813Potassium Cation2×

HCID 19660Carbonate Ion

HCID 26255Tetrafluoroborate

HCID 31374Dimethylacetamide

HCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)

HCID 4866470CID 4866470

HCID 582943973-Bromo-2-phenethyl-pyridine

Product 1

HCID 158731845,6-Dihydro-benzo[f]quinoline

Sources & evidence

ORD record: ord-e55e96d219ee4521ba974a2d72c3138f
Source dataset: Training data from https://doi.org/10.1039/C8SC04228D (6/10)
DOI: 10.1039/C8SC04228D

Reaction notes

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