Nitric Acid → HCID 23302428, compound

HRID 1953265Notes

Reaction equation

HRID 1953265 reaction equation
[CH:1]1([C:7]([C:9]2[CH:14]=[CH:13][C:12]([Cl:15])=[CH:11][CH:10]=2)=[O:8])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[N+:16]([O-])([OH:18])=[O:17]>>[CH:1]1([C:7]([C:9]2[CH:14]=[CH:13][C:12]([Cl:15])=[C:11]([N+:16]([O-:18])=[O:17])[CH:10]=2)=[O:8])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6]1

Participants

3

Reactant 2

HCID 944Nitric AcidHCID 115794564-CHLOROPHENYL CYCLOHEXYL KETONE

Product 1

HCID 23302428HCID 23302428, compound

Conditions

Temperature
-25 °C

Procedure

To 50 ml fuming nitric acid are added batchwise at -25° C. 6.4 g (28.8 mmol) of 4-(cyclohexylcarbonyl)-chlorobenzene. The solution is stirred for 10 minutes at -25° C. and then poured onto ice water. The precipitated product is suction filtered, washed with water and dried.

Workup

  1. additionpoured onto ice water
  2. filtrationfiltered
  3. washwashed with water
  4. customdried

Sources & evidence

ORD record
ord-e42da1b638a24a9ab3d1135ed5ef6b17
Source dataset
uspto-grants-2000_09
Patent number
US06114532

Reaction notes

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