Thionyl Chloride → HCID 18364483, compound

HRID 1953372Notes

Reaction equation

HRID 1953372 reaction equation
S(Cl)([Cl:3])=O.[CH3:5][C:6]1[CH:11]=[C:10]([CH3:12])[CH:9]=[C:8]([CH3:13])[C:7]=1[Bi:14]([C:24]1[C:29]([CH3:30])=[CH:28][C:27]([CH3:31])=[CH:26][C:25]=1[CH3:32])[C:15]1[C:20]([CH3:21])=[CH:19][C:18]([CH3:22])=[CH:17][C:16]=1[CH3:23]>CCCCCC>[Cl-:3].[Cl-:3].[CH3:23][C:16]1[CH:17]=[C:18]([CH3:22])[CH:19]=[C:20]([CH3:21])[C:15]=1[Bi:14]([C:24]1[C:25]([CH3:32])=[CH:26][C:27]([CH3:31])=[CH:28][C:29]=1[CH3:30])[C:7]1[C:6]([CH3:5])=[CH:11][C:10]([CH3:12])=[CH:9][C:8]=1[CH3:13]

Participants

4

Reactant 2

HCID 24386Thionyl ChlorideHCID 4670734HCID 4670734, compound

Product 1

HCID 18364483HCID 18364483, compound

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

Thionyl chloride (1.48 g, 11 mmol) was added to a solution of tris(2,4,6-trimethylphenyl)bismuthine (Example 14) (5.66 g, 10 mmol) in hexane (100 ml) at ambient temperature. The mixture was stirred for one hour and the precipitated product was isolated and recrystalized from ethanol. Yield: 5.70 g (90%).

Workup

  1. customthe precipitated product was isolated
  2. customrecrystalized from ethanol

Sources & evidence

ORD record
ord-767109a18ab04cbabcea6df251a1658d
Source dataset
uspto-grants-2000_09
Patent number
US06117412

Reaction notes

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