Salicylic Acid → Allyl salicylate

HRID 1956003Notes

Reaction equation

HRID 1956003 reaction equation
[C:1]([O-:10])(=[O:9])[C:2]1[C:3](=[CH:5][CH:6]=[CH:7][CH:8]=1)[OH:4].[Na+].[C:12](O)(=O)[C:13]1C(=CC=C[CH:19]=1)O.[OH-].[Na+]>O>[C:1]([O:10][CH2:19][CH:13]=[CH2:12])(=[O:9])[C:2]1[C:3](=[CH:5][CH:6]=[CH:7][CH:8]=1)[OH:4]

Participants

5

Reactant 3

HCID 338Salicylic AcidHCID 14798Sodium HydroxideHCID 16760658Sodium Salicylate

Product 1

HCID 66330Allyl salicylate

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A sodium salicylate solution, prepared from 69 g of salicylic acid (0.5 mol), 25 ml of water and 50 ml of an aqueous solution of 10N caustic soda, was introduced gradually at 60° C., over 6 hours.

Workup

  1. additionwas introduced gradually at 60° C., over 6 hours

Sources & evidence

ORD record
ord-1865cd107cba4a6882e3b6e84e6a51e3
Source dataset
uspto-grants-1998_07
Patent number
US05777151

Reaction notes

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