Chlorotrifluoroethylene → HCID 18663608, compound

HRID 1956583Notes

Reaction equation

HRID 1956583 reaction equation
C(F)(F)=C(Cl)F.[Br:7][C:8]1[C:18]2[O:17][C:16]3[CH:19]=[CH:20][CH:21]=[CH:22][C:15]=3[CH:14]=[C:13]([C:23](O)=[O:24])[C:12]=2[CH:11]=[CH:10][CH:9]=1>CCCCCC.C(OCC)(=O)C>[Br:7][C:8]1[C:18]2[O:17][C:16]3[CH:19]=[CH:20][CH:21]=[CH:22][C:15]=3[CH:14]=[C:13]([CH2:23][OH:24])[C:12]=2[CH:11]=[CH:10][CH:9]=1

Participants

4

Reactant 2

HCID 6594ChlorotrifluoroethyleneHCID 18663609HCID 18663609, compound

Product 1

HCID 18663608HCID 18663608, compoundYield 99%

Reagents, catalysts & solvents 1

HCID 21226206Ethyl acetate hexaneSolvent

Procedure

Preparation analogous to Example 12 f) from 6-bromo-dibenz[b,f]oxepine-10-carboxylic acid. Yield: 99% crude, brown oil; TLC (silica gel; hexane/ethyl acetate=7.3; UV): Rf =0.07; 1H-NMR (CDCl3, 200 MHz): 3.54 (s, 2H), 6.70-7.49 (m, 8H).

Sources & evidence

ORD record
ord-235e06343eac43bf94d669ed55fd2930
Source dataset
uspto-grants-1998_07
Patent number
US05780500

Reaction notes

Loading…