HuagongsheHuagongshe Chemistry Print Report · For research reference only
Chlorotrifluoroethylene → 7-Chlorodibenz[b,f]oxepin-10-methanol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Chlorotrifluoroethylene | HCID 6594 | — |
| Reactant | HCID 18663611 | HCID 18663611 | — |
| Solvent | Ethyl acetate hexane | HCID 21226206 | — |
| Product | 7-Chlorodibenz[b,f]oxepin-10-methanol | HCID 18663610 | 94% |
Reaction Steps
Preparation analogous to Example 12 f) aus 7-chloro-dibenz[b,f]oxepine-10-carboxylic acid. Yield: 94% in the form of an oil; TLC (silica gel; ethyl acetate/hexane=1:1; UV): Rf =0.38; 1H-NMR (CDCl3, 200 MHz): 1.72 (sbr, 1H); 4.67 (s, 2H); 6.91 (s, 1H); 7.10-7.40 (m, 7H) ; MS: 260/258 (M+), 217/215.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05780501 |
| Source dataset | uspto-grants-1998_07 |
| ORD ID | ord-68deb7c32c1144f2a765b5648b7690d1 |
| Source note | uspto-grants-1998_07 |