HRID1956950

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：Cc1cc(C)cc(P(c2cc(C)cc(C)c2)c2ccc3ccccc3c2-c2c(P(c3cc(C)cc(C)c3)c3cc(C)cc(C)c3)ccc3ccccc23)c1

HCID4189905

1,1′-[(1R)-[1,1′-Binaphthalene]-2,2′-diyl]bis[1,1-bis(3,5-dimethylphenyl)phosphine

C52H48P2

4 次

PRODUCTS

生成物

结构：C[C@@H](C[C@H](C)P(c1ccccc1)c1ccccc1)P(c1ccccc1)c1ccccc1

HCID2734567

(2S,4S)-(-)-2,4-BIS(DIPHENYLPHOSPHINO)PENTANE

C29H30P2

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID8471

Triethylamine

C6H15N

2 次

PROCEDURE

实验过程

Among these transition metal complexes, preferable ones include [Ru2 Cl4 (DM-BINAP)2 ]NEt3, [Ru2Cl4(OcH-BINAP)2 ]NEt3, [Ru2Cl4 (OcH-DM-BINAP)2 ]NEt3, [RuI(p-cymene)(DM-BINAP)]I, [RuCl(p-cymene)(DM-BINAP)]Cl, [RuBr(p-cymene)(DM-BINAP)]Br, [RuI(benzene)(DM-BINAP)]I, [RuCl(benzene)(DM-BINAP)]Cl, [RuBr(benzene)(DM-BINAP)]Br, [RuI(p-cymene)(OcH-BINAP)]I, [RuCl(p-cymene)(OcH-BINAP)]Cl, [RuBr(p-cymene)(OcH-BINAP)]Br, [RuI(benzene)(OcH-BINAP)]I, [RuCl(benzene)(OcH-BINAP)]Cl, [RuBr(benzene)(OcH-BINAP)]Br, [RuI(p-cymene)(OcH-DM-BINAP)]I, [RuCl(p-cymene)(OcH-DM-BINAP)]Cl, [RuBr(p-cymene)(OcH-DM-BINAP)]Br, [RuI(benzene)(OcH-DM-BINAP)]I, [RuCl(benzene)(OcH-DM-BINAP)]Cl and [RuBr(benzene)(OcH-DM-BINAP)]Br, and still preferable ones include [RU2Cl4 (DM-BINAP )2 ]NEt3, [Ru2Cl4 (OcH-BINAP)2 ]NEt3 and [Ru2 Cl4 (OcH-DM-BINAP)2 ]NEt3.