m-Chloroperbenzoic acid → HCID 19068258, compound

HRID 1957685Notes

Reaction equation

HRID 1957685 reaction equation
[C:1]12([C:11]3[CH:12]=[C:13]([CH2:19][S:20][C:21]4[CH:30]=[CH:29][C:24]([C:25]([O:27][CH3:28])=[O:26])=[CH:23][CH:22]=4)[CH:14]=[CH:15][C:16]=3[O:17][CH3:18])[CH2:10][CH:5]3[CH2:6][CH:7]([CH2:9][CH:3]([CH2:4]3)[CH2:2]1)[CH2:8]2.ClC1C=CC=C(C(OO)=[O:39])C=1>>[C:1]12([C:11]3[CH:12]=[C:13]([CH2:19][S:20]([C:21]4[CH:30]=[CH:29][C:24]([C:25]([O:27][CH3:28])=[O:26])=[CH:23][CH:22]=4)=[O:39])[CH:14]=[CH:15][C:16]=3[O:17][CH3:18])[CH2:10][CH:5]3[CH2:4][CH:3]([CH2:9][CH:7]([CH2:6]3)[CH2:8]1)[CH2:2]2

Participants

3

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 19068250HCID 19068250, compound

Product 1

HCID 19068258HCID 19068258, compound

Procedure

In a manner analogous to that of Example 2(b), 2.96 g (7 mmol) of methyl 4-[3-(1-adamantyl)-4-methoxyphenylmethylthio]benzoate were reacted with 1.42 g (7 mmol) of meta-chloroperbenzoic acid and 2.33 g (76%) of the expected methyl ester, having a melting point of 151°-2° C., were recovered.

Workup

  1. customwere recovered

Sources & evidence

ORD record
ord-b2cc93d45baa480096b24868fd899661
Source dataset
uspto-grants-1998_07
Patent number
US05786379

Reaction notes

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