Cyclopropane → Heptane, 2,2,6,6-tetramethyl-4-methylene-

HRID 1967643Notes

Reaction equation

[CH2:1]([C:6]([CH2:8][C:9]([CH3:12])([CH3:11])[CH3:10])=O)[C:2]([CH3:5])([CH3:4])[CH3:3].[CH2:13]1CC1>>[CH3:3][C:2]([CH3:5])([CH2:1][C:6](=[CH2:13])[CH2:8][C:9]([CH3:12])([CH3:11])[CH3:10])[CH3:4]

Participants

Reactant 2

HCID 6351Cyclopropane

HCID 1382442,2,6,6-Tetramethyl-4-heptanone

Product 1

HCID 67334Heptane, 2,2,6,6-tetramethyl-4-methylene-

Procedure

The ratio between dineopentyl ketone and the cyclopropane derivative in this case was 2.5 g/g.

Sources & evidence

ORD record: ord-a6e4b2de285a4a569539dff89af98ebd
Source dataset: uspto-grants-2013_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08420866B2

Reaction notes

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