huagongshe.com
HRID1970989

反应详情

EQUATION

反应方程式

HRID 1970989 的结构方程式

REACTANTS

反应物

1
结构：CC(C)(C)[Si](C)(C)OC1CCC(N=[N+]=[N-])CC1F
HCID59543137

未命名化合物

PRODUCTS

生成物

1
结构：CC(C)(C)[Si](C)(C)OC1CCC(N)CC1F
HCID59543122

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

2
结构：[Pd]
催化剂HCID23938

Palladium

Pd

结构：CO
溶剂HCID887

Methanol

CH4O

2 次

PROCEDURE

实验过程

To a stirred solution [(4-azido-2-fluorocyclohexyl)oxy](tert-butyl)dimethylsilane (1.0 g, 3.66 mmol) in MeOH (15 mL) was added Pd/C in MeOH. The flask was evacuated and filled with hydrogen several times, and left to stir overnight under hydrogen atmosphere. The mixture was diluted with DCM, filtered through a pad of Celite, and concentrated to afford the title compound.

WORKUP

后处理

  1. customThe flask was evacuated
  2. additionfilled with hydrogen several times
  3. waitleft
  4. additionThe mixture was diluted with DCM
  5. filtrationfiltered through a pad of Celite
  6. concentrationconcentrated