Isopropylamine → HCID 21389351, compound

HRID 1973083Notes

Reaction equation

HRID 1973083 reaction equation
[CH3:1][CH:2]1[CH2:7][CH2:6][C:5](=O)[CH2:4][CH2:3]1.[CH:9]([NH2:12])([CH3:11])[CH3:10]>>[CH3:10][CH:9]([N:12]=[C:5]1[CH2:6][CH2:7][CH:2]([CH3:1])[CH2:3][CH2:4]1)[CH3:11]

Participants

3

Reactant 2

HCID 6363IsopropylamineHCID 115254-Methylcyclohexanone

Product 1

HCID 21389351HCID 21389351, compound

Procedure

To a mixture of 600 g. 4-methyl cyclohexanone and 1 l. isopropylamine are added 500 g. Linde Type 3A molecular sieves. The mixture is allowed to stand overnight at room temperature, after which the sieves are removed by filtration and the excess of isopropylamine is removed in vacuo at room temperature. The residual oil is 1-methyl-N-(4-methyl cyclohexylidene)-ethylamine.

Workup

  1. additionTo a mixture of 600 g
  2. customafter which the sieves are removed by filtration
  3. customthe excess of isopropylamine is removed in vacuo at room temperature

Sources & evidence

ORD record
ord-8633a965d21348e0acad6067a624c848
Source dataset
uspto-grants-1976_12
Patent number
US03996227

Reaction notes

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