Ammonia → HCID 21491941, compound

HRID 1973548Notes

Reaction equation

HRID 1973548 reaction equation
[NH3:1].[CH:2]([C:5]1[CH:10]=[C:9]([C:11]([F:14])([F:13])[F:12])[C:8]([CH:15]([CH3:17])[CH3:16])=[CH:7][C:6]=1[S:18](F)(=[O:20])=[O:19])([CH3:4])[CH3:3]>>[CH:2]([C:5]1[CH:10]=[C:9]([C:11]([F:14])([F:13])[F:12])[C:8]([CH:15]([CH3:17])[CH3:16])=[CH:7][C:6]=1[S:18]([NH2:1])(=[O:20])=[O:19])([CH3:4])[CH3:3]

Participants

3

Reactant 2

HCID 222AmmoniaHCID 21491954HCID 21491954, compound

Product 1

HCID 21491941HCID 21491941, compound

Procedure

A mixture of ammonia, 25 parts, and 2,5-diisopropyl-4-trifluoromethylbenzenesulfonyl fluoride, 7 parts, is heated for 4 hours at 100° in a Hastelloy-lined bomb. After removal of the ammonia, the crude product is stirred with water, filtered and dried. Pure product, m.p. 171°-174°, is obtained after vacuum sublimation.

Workup

  1. customAfter removal of the ammonia
  2. filtrationfiltered
  3. customdried
  4. customPure product, m.p. 171°-174°, is obtained after vacuum sublimation

Sources & evidence

ORD record
ord-1257aa2115f54c7e804a13930feaa816
Source dataset
uspto-grants-1976_12
Patent number
US03997603

Reaction notes

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