Aluminium lithium hydride → HCID 70619409, compound

HRID 1973697Notes

Reaction equation

HRID 1973697 reaction equation
[C:1]1([C:7]([C:32]2[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=2)([C:26]2[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=2)[CH2:8][C:9]([N:11]2[CH2:15][C:14]3[C:16]4[C:25]5[C:20](=[CH:21][CH:22]=[CH:23][C:24]=5[C:13]=3[CH2:12]2)[CH:19]=[CH:18][CH:17]=4)=O)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[H-].[Al+3].[Li+].[H-].[H-].[H-]>O1CCCC1>[C:32]1([C:7]([C:1]2[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=2)([C:26]2[CH:27]=[CH:28][CH:29]=[CH:30][CH:31]=2)[CH2:8][CH2:9][N:11]2[CH2:15][C:14]3[C:16]4[C:25]5[C:20](=[CH:21][CH:22]=[CH:23][C:24]=5[C:13]=3[CH2:12]2)[CH:19]=[CH:18][CH:17]=4)[CH:33]=[CH:34][CH:35]=[CH:36][CH:37]=1

Participants

4

Reactant 2

HCID 21226445Aluminium lithium hydrideHCID 131710574HCID 131710574, compound

Product 1

HCID 70619409HCID 70619409, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

Following the procedures set out in Example 1, 3.0 parts of 3,3,3-triphenylpropionyl chloride and 2.0 parts of acenaphto[1,2-C]pyrrolidene are reacted to provide 8-(3,3,3-triphenylpropionyl)acenaphto[1,2-C]pyrroldine, melting at 159°-168°. 3.5 Parts of this amide are reacted with 3.6 parts of lithium aluminum hydride in tetrahydrofuran to provide 8-(3,3,3-triphenylpropyl)acenaphtho[1,2-C]pyrrolidine. This compound has the following structural formula. ##STR44##

Sources & evidence

ORD record
ord-7d3683602cbd4e46accdc6f4e101f290
Source dataset
uspto-grants-1976_12
Patent number
US03998832

Reaction notes

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