p-Chlorothiophenol → HCID 54507390, compound

HRID 1973712Notes

Reaction equation

HRID 1973712 reaction equation
[CH2:1]([N:4]=[C:5]=[O:6])[CH:2]=[CH2:3].[Cl:7][C:8]1[CH:13]=[CH:12][C:11]([SH:14])=[CH:10][CH:9]=1>CSC>[Cl:7][C:8]1[CH:13]=[CH:12][C:11]([S:14][CH2:3][CH2:2][CH2:1][N:4]=[C:5]=[O:6])=[CH:10][CH:9]=1

Participants

4

Reactant 2

HCID 7815p-ChlorothiophenolHCID 15123Allyl isocyanate

Product 1

HCID 54507390HCID 54507390, compound

Reagents, catalysts & solvents 1

HCID 1068Dimethyl SulfideSolvent

Procedure

A solution of 41.5 grams (0.5 mole) of allyl isocyanate and 72.25 grams (0.5 mole) of p-chlorobenzenethiol in 50 ml dimethyl sulfide was irradiated with an ultraviolet lamp in the manner described in Example 1. Nmr indicated that in 48 hours 32% of the allylic double bonds reacted with the thiol to form the allylic monoadduct, i.e. 3-p-chlorophenylthiopropyl isocyanate. No other products could be observed.

Workup

  1. customindicated that in 48 hours 32% of the allylic double bonds

Sources & evidence

ORD record
ord-155e87f486d64206bcfbb977569628a8
Source dataset
uspto-grants-1976_12
Patent number
US03998866

Reaction notes

Loading…