1,4-Dicyanobenzene → 1,4-Cyclohexanedimethanamine

HRID 1973748Notes

Reaction equation

HRID 1973748 reaction equation
[C:1](#[N:10])[C:2]1[CH:9]=[CH:8][C:5]([C:6]#[N:7])=[CH:4][CH:3]=1>[Rh]>[NH2:7][CH2:6][CH:5]1[CH2:8][CH2:9][CH:2]([CH2:1][NH2:10])[CH2:3][CH2:4]1

Participants

3

Reactant 1

HCID 121721,4-Dicyanobenzene

Product 1

HCID 173541,4-Cyclohexanedimethanamine

Reagents, catalysts & solvents 1

HCID 23948RhodiumCatalyst

Procedure

Following the details of the above Example I, when terephthalonitrile was reduced over a 60 minute period using 6.0 g. of the supported rhodium catalyst, 1,4-bisaminomethlycyclohexane was obtained and 100% conversion of terephthalonitrile had occurred.

Sources & evidence

ORD record
ord-9c405b8adfff485dbfaaf99d88de9078
Source dataset
uspto-grants-1976_12
Patent number
US03998881

Reaction notes

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