HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydroxylamine → 1-Methoxy-1-methyl-3-(4,5,6,7-tetrahydrobenzo[b]thien-4-yl)urea
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydroxylamine | HCID 787 | — |
| Reactant | O-Methylhydroxylamine | HCID 4113 | — |
| Reactant | N,O-Dimethylhydroxylamine | HCID 14232 | — |
| Reactant | Propargylamine | HCID 239041 | — |
| Reactant | O-Butylhydroxylamine | HCID 3014370 | — |
| Reactant | 4-Isocyanato-7-methoxy-4,5,6,7-tetrahydro-1-benzothiophene | HCID 21490952 | — |
| Product | 1-Methoxy-1-methyl-3-(4,5,6,7-tetrahydrobenzo[b]thien-4-yl)urea | HCID 20348950 | — |
Reaction Steps
Similarly, 4,5,6,7-tetrahydro-7-methoxybenzo[b]-thien-4-ylisocyanate is allowed to react with propargylamine, methoxyamine, hydroxylamine, n-butoxyamine and methylmethoxyamine to afford 1-propynyl-, 1-methoxy-, 1-hydroxy-, 1(-n-butoxy)-, and 1-methyl-1-methoxy-3-(4,5,6,7-tetrahydrobenzo[b]thien-4-yl)urea, respectively.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03998959 |
| Source dataset | uspto-grants-1976_12 |
| ORD ID | ord-f00cf80485694188a49308dd00decd0d |
| Source note | uspto-grants-1976_12 |