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Perfluorooctyl iodide → Methyl perfluorooctyl sulphide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Perfluorooctyl iodide | HCID 10491 | — |
| 反応物 | Dimethyl Disulfide | HCID 12232 | — |
| 反応物 | Sodium Phosphate, Dibasic | HCID 24203 | — |
| 反応物 | Sodium Dithionite | HCID 24489 | — |
| 溶媒 | Water | HCID 962 | — |
| 溶媒 | Dimethylformamide | HCID 6228 | — |
| 生成物 | Methyl perfluorooctyl sulphide | HCID 10504381 | 20% |
反応手順
Perfluorooctyl iodide (5.5 g), sodium dithionite (3 g), sodium hydrogen phosphate (3 g) and methyl disulphide (1 g) are stirred in dimethylformamide (10 cc) and water (5 cc) for 6 hours. After the usual treatment, methyl perfluorooctyl sulphide is obtained in 20% yield.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05283337 |
| 出典データセット | uspto-grants-1994_02 |
| ORD ID | ord-46b8bcc862df406cb7effd7aa6decbca |
| 出典メモ | uspto-grants-1994_02 |