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HRID1974787

反应详情

EQUATION

反应方程式

HRID 1974787 的结构方程式

REACTANTS

反应物

4
结构：FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)I
HCID10491

Perfluorooctyl iodide

C8F17I

结构：CSSC
HCID12232

Methyl disulfide

C2H6S2

结构：O=P([O-])([O-])O.[Na+].[Na+]
HCID24203

Dibasic sodium phosphate

HNa2O4P

结构：O=S([O-])S(=O)[O-].[Na+].[Na+]
HCID24489

Dithionous acid, disodium salt

Na2O4S2

PRODUCTS

生成物

1
结构：CSC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F
HCID10504381

未命名化合物

收率 20%

AUXILIARIES

试剂、催化剂与溶剂

2
结构：O
溶剂HCID962

Water

H2O

结构：CN(C)C=O
溶剂HCID6228

N,N-Dimethylformamide

C3H7NO

PROCEDURE

实验过程

Perfluorooctyl iodide (5.5 g), sodium dithionite (3 g), sodium hydrogen phosphate (3 g) and methyl disulphide (1 g) are stirred in dimethylformamide (10 cc) and water (5 cc) for 6 hours. After the usual treatment, methyl perfluorooctyl sulphide is obtained in 20% yield.