Ethyl 3-hydroxybenzoate → HCID 22406612, compound

HRID 1975686Notes

Reaction equation

HRID 1975686 reaction equation
Br[CH2:2][C:3]1[CH:12]=[CH:11][C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=1.[OH:13][C:14]1[CH:15]=[C:16]([CH:22]=[CH:23][CH:24]=1)[C:17]([O:19][CH2:20][CH3:21])=[O:18]>>[CH:4]1[C:5]2[C:10](=[CH:9][CH:8]=[CH:7][CH:6]=2)[CH:11]=[CH:12][C:3]=1[CH2:2][O:13][C:14]1[CH:15]=[C:16]([CH:22]=[CH:23][CH:24]=1)[C:17]([O:19][CH2:20][CH3:21])=[O:18]

Participants

3

Reactant 2

HCID 24522Ethyl 3-hydroxybenzoateHCID 703202-Bromomethylnaphthalene

Product 1

HCID 22406612HCID 22406612, compoundYield 85%

Procedure

In an analogous procedure to that described in Example 1, 2-bromomethylnaphthalene was reacted with ethyl 3-hydroxybenzoate to give ethyl 3-(naphth-2-ylmethoxy)benzoate in 85% yield, m.p. 45°-46.5° C.

Sources & evidence

ORD record
ord-3fa11932178f4495a90f9d599198d7bf
Source dataset
uspto-grants-1994_02
Patent number
US05288742

Reaction notes

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