m-Chloroperbenzoic acid → HCID 88479282, compound

HRID 1975794Notes

Reaction equation

HRID 1975794 reaction equation
[CH3:1][S:2]([OH:5])(=[O:4])=[O:3].[S:6]1[CH2:10][CH2:9][C:8]2[CH:11]=[C:12]([CH2:15][CH2:16][N:17]([CH2:19][C@H:20]3[C:29]4[C:24](=[C:25]([O:30][CH3:31])[CH:26]=[CH:27][CH:28]=4)[CH2:23][CH2:22][CH2:21]3)[CH3:18])[CH:13]=[CH:14][C:7]1=2.ClC1C=CC=C(C(OO)=[O:40])C=1>>[CH3:1][S:2]([OH:5])(=[O:4])=[O:3].[O:40]=[S:6]1[C:7]2[CH:14]=[CH:13][C:12]([CH2:15][CH2:16][N:17]([CH2:19][C@H:20]3[C:29]4[C:24](=[C:25]([O:30][CH3:31])[CH:26]=[CH:27][CH:28]=4)[CH2:23][CH2:22][CH2:21]3)[CH3:18])=[CH:11][C:8]=2[CH2:9][CH2:10]1

Participants

3

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 86747616HCID 86747616, compound

Product 1

HCID 88479282HCID 88479282, compound

Procedure

The product from Example 26 is treated with one equivalent of m-chloroperbenzoic acid to yield the title compound.

Sources & evidence

ORD record
ord-fe6004de6a6b4bb29028466a93b8b506
Source dataset
uspto-grants-1994_02
Patent number
US05288749

Reaction notes

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