m-Chloroperbenzoic acid → HCID 88479326, compound

HRID 1975796Notes

Reaction equation

HRID 1975796 reaction equation
[CH3:1][S:2]([OH:5])(=[O:4])=[O:3].S1[C:10]2[CH:11]=[C:12]([CH2:15][CH2:16][N:17]([CH2:19][C@H:20]3[C:29]4[C:24](=[C:25]([O:30][CH3:31])[CH:26]=[CH:27][CH:28]=4)[CH2:23][CH2:22][CH2:21]3)[CH3:18])[CH:13]=[CH:14][C:9]=2NC1.Cl[C:33]1C=CC=C(C(OO)=O)C=1>>[CH3:1][S:2]([OH:5])(=[O:4])=[O:3].[O:5]=[S:2]1[C:1]2[CH:13]=[C:12]([CH2:15][CH2:16][N:17]([CH2:19][C@H:20]3[C:29]4[C:24](=[C:25]([O:30][CH3:31])[CH:26]=[CH:27][CH:28]=4)[CH2:23][CH2:22][CH2:21]3)[CH3:18])[CH:11]=[CH:10][C:9]=2[CH2:14][CH2:33]1

Participants

3

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 86747617HCID 86747617, compound

Product 1

HCID 88479326HCID 88479326, compound

Procedure

The product from Example 54 is treated with one equivalent of m-chloroperbenzoic acid to yield the title compound.

Sources & evidence

ORD record
ord-e8dd08240a4b42c68037dbec9004b346
Source dataset
uspto-grants-1994_02
Patent number
US05288749

Reaction notes

Loading…