反应详情

The reaction was conducted in the same manner as Example 1 except using 1 mmol of oxalic acid instead of 98% by weight of sulfuric acid, the pH of the mixture was 3.7, and as a result, adamantane was converted into adamantanone (yield 8%) and 1-hydroxyadamantanone (yield 2%) with a conversion of 99%. Incidentally, excepting the above, 1-adamantanol (yield 26%), 1,3-adamantanediol (yield 33%) and other products (polyol such as adamantanetriol) (yield 30%) were formed.