Oxalic Acid → Adamantanone

HRID 1977081노트

반응식

HRID 1977081 반응식
[C:1]([OH:6])(=O)[C:2](O)=[O:3].S(=O)(=O)(O)O.[CH:12]12[CH2:21][CH:16]3C[CH:18]([CH2:20][CH:14]([CH2:15]3)[CH2:13]1)[CH2:19]2>>[CH:16]12[CH2:21][CH:12]3[CH2:13][CH:14]([CH2:20][CH:2]([CH2:19]3)[C:1]1=[O:6])[CH2:15]2.[OH:6][C:1]12[CH2:21][CH:12]3[CH2:13][CH:14]([CH2:20][CH:18]([CH2:19]3)[C:2]1=[O:3])[CH2:15]2

참가 물질

5

반응물 3

HCID 971Oxalic AcidHCID 1118Sulfuric AcidHCID 9238Adamantane

생성물 2

HCID 64151Adamantanone수율 8%HCID 109648841-Hydroxyadamantan-2-one수율 2%

실험 절차

The reaction was conducted in the same manner as Example 1 except using 1 mmol of oxalic acid instead of 98% by weight of sulfuric acid, the pH of the mixture was 3.7, and as a result, adamantane was converted into adamantanone (yield 8%) and 1-hydroxyadamantanone (yield 2%) with a conversion of 99%. Incidentally, excepting the above, 1-adamantanol (yield 26%), 1,3-adamantanediol (yield 33%) and other products (polyol such as adamantanetriol) (yield 30%) were formed.

출처 및 근거

ORD 기록
ord-29bbad28e2c64e2c9d288b3b3b9ae291
출처 데이터셋
uspto-grants-2001_05
특허 번호
US06232258B1

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