HuagongsheHuagongshe Chemistry Print Report · For research reference only
Oxygen → Methyl 3-hydroxyadamantane-1-carboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Oxygen | HCID 977 | — |
| Reactant | Tricyclo(3.3.1.13,7)decane-1-carboxylic acid, methyl ester | HCID 136553 | — |
| Product | Methyl 3-hydroxyadamantane-1-carboxylate | HCID 144304 | 42% |
Reaction Steps
The oxidization in an oxygen atmosphere was conducted in the same manner as in Preparation Example 1 except that 1-methoxycarbonyladamantane was used instead of the adamantane, and, as a result, a 1-methoxycarbonyl-3-hydroxyadamantane (yield: 42%) and a 1-methoxycarbonyl-3,5-hydroxyadamantane (yield : 33%) were obtained with a conversion of 91%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06235851B1 |
| Source dataset | uspto-grants-2001_05 |
| ORD ID | ord-06c075dd70014f3daf776c4f4a9c7eff |
| Source note | uspto-grants-2001_05 |