HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrogen Bromide → 1,6,12-Triazadodecane Trihydrochloride
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrogen Bromide | HCID 260 | — |
| Reactant | Phenol | HCID 996 | — |
| Reactant | Dichloromethane | HCID 6344 | — |
| Reactant | HCID 10594392 | HCID 10594392 | — |
| Product | 1,6,12-Triazadodecane Trihydrochloride | HCID 21996650 | 50% |
Reaction Steps
HBr (30% in HOAC, 33 mL), 41 (2.43 g, 6.83 mmol), and phenol (6 g, 60 mmol) in CH2Cl2 were reacted, and product was isolated by the procedure of 2 to give 0.97 g (50%) of 20 as a hygroscopic solid: NMR (D2O) δ 1.47 (m, 2 H), 1.70-1.80 (m, 8 H), 3.00-3.10 (m, 8 H). Anal. (C9H26Cl3N3) C, H, N.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06235794B1 |
| Source dataset | uspto-grants-2001_05 |
| ORD ID | ord-d4edea49c79649d493021d85eb2dad07 |
| Source note | uspto-grants-2001_05 |