HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethylformamide → HCID 54377917, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethylformamide | HCID 6228 | — |
| Reactant | Methyl (methylsulfinyl)methyl sulfide | HCID 99129 | — |
| Reactant | Methyl 5-chloro-1-benzothiophene-2-carboxylate | HCID 23340399 | — |
| Product | HCID 54377917 | HCID 54377917 | — |
| Product | HCID 54416893 | HCID 54416893 | — |
Reaction Steps
Methylthio α-oxo-α-(5-chloro-2-benzothienyl)acetate was prepared by reacting 26.8 g of methyl (5-chloro-2-benzothienyl)formate with 21.4 g of methyl methylthiomethyl sulfoxide in 500 ml of N,N-dimethylformamide to give 1-oxo-1-(5-chloro-2-benzothienyl)-2-methylthio-2-methylsulfinylethane, which was then reacted with sodium para periodate in acetic anhydride and formic acid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04482553 |
| Source dataset | uspto-grants-1984_11 |
| ORD ID | ord-2441d6f5763f4437b29cbc7a388d729b |
| Source note | uspto-grants-1984_11 |