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HRID1979689

反应详情

EQUATION

反应方程式

HRID 1979689 的结构方程式

REACTANTS

反应物

3
结构：CN(C)C=O
HCID6228

N,N-Dimethylformamide

C3H7NO

结构：CSCS(C)=O
HCID99129

Methane, (methylsulfinyl)(methylthio)-

C3H8OS2

结构：COC(=O)c1cc2cc(Cl)ccc2s1
HCID23340399

Methyl 5-chloro-1-benzothiophene-2-carboxylate

C10H7ClO2S

PRODUCTS

生成物

2
结构：CSOC(=O)C(=O)c1cc2cc(Cl)ccc2s1
HCID54377917

未命名化合物

结构：CSC(C(=O)c1cc2cc(Cl)ccc2s1)S(C)=O
HCID54416893

未命名化合物

PROCEDURE

实验过程

Methylthio α-oxo-α-(5-chloro-2-benzothienyl)acetate was prepared by reacting 26.8 g of methyl (5-chloro-2-benzothienyl)formate with 21.4 g of methyl methylthiomethyl sulfoxide in 500 ml of N,N-dimethylformamide to give 1-oxo-1-(5-chloro-2-benzothienyl)-2-methylthio-2-methylsulfinylethane, which was then reacted with sodium para periodate in acetic anhydride and formic acid.