Chloroacetyl chloride → HCID 20439056, compound

HRID 1979802Notes

Reaction equation

HRID 1979802 reaction equation
[Cl:1][CH2:2][C:3](Cl)=[O:4].[Cl-:6].[Al+3].[Cl-].[Cl-].[Cl:10][CH:11]=[CH:12][Cl:13]>>[Cl:10][CH:11]([C:3]([CH2:2][Cl:1])=[O:4])[CH:12]([Cl:6])[Cl:13]

Participants

4

Reactant 3

HCID 6577Chloroacetyl chlorideHCID 109001,2-DichloroethyleneHCID 6451240Aluminum(III) Chloride

Product 1

HCID 20439056HCID 20439056, compound

Procedure

The reaction of chloroacetyl chloride and aluminum chloride with a molar excess of 1,2-dichloroethylene has been reported by Catch et al., J. Chem. Soc. (London) 278 (1948) to afford chloromethyl 1,2,2-trichloroethyl ketone. McLamore et al., J. Org. Chem., 20, 109 (1955) have reported propionyl chloride to react with 1,2-dichloroethylene to provide ethyl 1,2,2-trichloroethyl ketone.

Sources & evidence

ORD record
ord-9450811d8f1545ac971651f6a5b38783
Source dataset
uspto-grants-1984_11
Patent number
US04482723

Reaction notes

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