HRID1979836

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID420841

o-Allylhydroxylamine

C3H7NO

结构：CCC(=O)C1=C(O)CC(c2ccc(NS(C)(=O)=O)cc2)CC1=O

HCID178458872

未命名化合物

PRODUCTS

生成物

结构：C=CCON=C(CC)C1=C(O)CC(c2ccc(NS(C)(=O)=O)cc2)CC1=O

HCID136199969

未命名化合物

收率 68.8%

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID8028

Tetrahydrofuran

C4H8O

PROCEDURE

实验过程

Into 10 ml of tetrahydrofuran was dissolved 1.0 g of 5-(4-methanesulfonamidophenyl)-3-hydroxy-2-propionyl-2-cyclohexen-1-one and to the solution was added 0.5 g of allyloxyamine. The mixture was kept at room temperature for 15 hours and then it was treated with similar process in Example 1. Thus, 0.8 g of the objective compound was obtained. It was colorless crystals having a melting point of 134°-135° C.

WORKUP

后处理

additionit was treated with similar process in Example 1