Dichloromethane → HCID 13363448, compound

HRID 1980103Notes

Reaction equation

HRID 1980103 reaction equation
[CH3:1][N:2]([S:6]Cl)[C:3]([Cl:5])=[O:4].[CH2:8]([Cl:12])[C:9](=[CH2:11])[CH3:10].C(Cl)[Cl:14]>>[CH3:1][N:2]([S:6][C:9]([CH3:10])([CH2:11][Cl:14])[CH2:8][Cl:12])[C:3]([Cl:5])=[O:4]

Participants

4

Reactant 3

HCID 6344DichloromethaneHCID 112413-Chloro-2-methyl-1-propeneHCID 20437446HCID 20437446, compound

Product 1

HCID 13363448HCID 13363448, compound

Procedure

To a solution of 16.0 g of N-methyl-N-chlorosulfenyl carbamoyl chloride in 100 ml of methylene chloride was added 12.0 g of methallyl chloride with stirring, at room temperature. On slight heating there was a spontaneous exotherm which raised the temperature of the reaction mixture to 39° C. On removal of the solvent under reduced pressure 19.6 g of oil was obtained, N25D 1.5379.

Workup

  1. temperatureOn slight heating there
  2. temperatureraised the temperature of the reaction mixture to 39° C
  3. customOn removal of the solvent under reduced pressure 19.6 g of oil
  4. customwas obtained

Sources & evidence

ORD record
ord-75700897304d47278d0b98aa8a125ab5
Source dataset
uspto-grants-1984_11
Patent number
US04485113

Reaction notes

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