2,3-Octanedione → HCID 86740024, compound

HRID 1980803Notes

Reaction equation

[Ce+4:1].[F:2][C:3]([F:20])([C:13]([F:19])([F:18])[C:14]([F:17])([F:16])[F:15])[C:4](=[O:12])[CH2:5][C:6](=[O:11])[C:7]([CH3:10])([CH3:9])[CH3:8].CC(=O)C(=O)CCCCC>>[Ce+4:1].[F:2][C:3]([F:20])([C:13]([F:18])([F:19])[C:14]([F:15])([F:16])[F:17])[C:4](=[O:12])[CH2:5][C:6](=[O:11])[C:7]([CH3:10])([CH3:9])[CH3:8].[F:2][C:3]([F:20])([C:13]([F:18])([F:19])[C:14]([F:15])([F:16])[F:17])[C:4](=[O:12])[CH2:5][C:6](=[O:11])[C:7]([CH3:10])([CH3:9])[CH3:8].[F:2][C:3]([F:20])([C:13]([F:18])([F:19])[C:14]([F:15])([F:16])[F:17])[C:4](=[O:12])[CH2:5][C:6](=[O:11])[C:7]([CH3:10])([CH3:9])[CH3:8].[F:2][C:3]([F:20])([C:13]([F:18])([F:19])[C:14]([F:15])([F:16])[F:17])[C:4](=[O:12])[CH2:5][C:6](=[O:11])[C:7]([CH3:10])([CH3:9])[CH3:8]

Participants

Reactant 3

HCID 114492,3-Octanedione

HCID 28614(Heptafluorobutanoyl)pivaloylmethane

HCID 119438Cerium(4+)2×

Product 1

HCID 86740024HCID 86740024, compound

Procedure

combining the cerium (IV) solution with deprotonated 6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedione to react the octanedione with the cerium (IV), and to thereby yield a tetrakis-(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedione) cerium (IV) product.

Sources & evidence

ORD record: ord-6db27ae7105d446c9c6a7fdeeeb7b9b9
Source dataset: uspto-grants-1985_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04511515

Reaction notes

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