Isophorone → Hydrogen Peroxide

HRID 1981070Notes

Reaction equation

[O:1]=C1CC(C)(C)CC(C)=C1.[O:11]=[O+:12][O-].[CH3:14][C:15]([CH3:24])([CH2:20][C:21](=[O:23])C)[CH2:16][C:17]([OH:19])=[O:18]>>[CH3:24][C:15]([CH3:14])([CH2:16][C:17]([OH:19])=[O:18])[CH2:20][C:21]([OH:23])=[O:1].[OH:11][OH:12]

Participants

Reactant 3

HCID 6544Isophorone

HCID 24823Ozone

HCID 113326103,3-Dimethyl-5-oxohexanoic acid

Product 2

HCID 784Hydrogen Peroxide

HCID 209843,3-Dimethylglutaric acid

Procedure

The process of the invention converts isophorone into an ozone-addition product, which is then converted into 3,3-dimethyl-5-oxo-hexanoic acid. From the latter, 3,3-dimethylglutaric acid is produced by means of hydrogen peroxide treatment.

Sources & evidence

ORD record: ord-a8f084da2ee54eeabf398fa2336a5575
Source dataset: uspto-grants-1985_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04511734

Reaction notes

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