Methylamine → HCID 13502057, compound

HRID 1981077Notes

Reaction equation

HRID 1981077 reaction equation
[CH3:1][S:2]([CH2:5][CH2:6][S:7](Cl)(=[O:9])=[O:8])(=[O:4])=[O:3].[CH3:11][NH2:12]>C(Cl)(Cl)Cl.O>[CH3:11][NH:12][S:7]([CH2:6][CH2:5][S:2]([CH3:1])(=[O:4])=[O:3])(=[O:9])=[O:8]

Participants

5

Reactant 2

HCID 6329MethylamineHCID 1254146071350-98-6

Product 1

HCID 13502057HCID 13502057, compound

Reagents, catalysts & solvents 2

HCID 962WaterSolventHCID 6212ChloroformSolvent

Procedure

To a stirred mixture of 2-(methylsulfonyl)ethanesulfonyl chloride in 50 ml chloroform, 15.5 g (0.2 mole) 40% methylamine in water were added slowly. The reaction mixture was stirred one hour and then filtered. The filtrate was washed with water. The organic phase was separated and then stripped. Cold ether was added to the residue; the resulting mixture was stirred. Filtration of the ether mixture gave 11.0 g of the above-identified product as a white solid, mp. 116°-117° C.

Workup

  1. additionwere added slowly
  2. filtrationfiltered
  3. washThe filtrate was washed with water
  4. customThe organic phase was separated
  5. additionCold ether was added to the residue
  6. stirringthe resulting mixture was stirred
  7. filtrationFiltration of the ether mixture

Sources & evidence

ORD record
ord-8b6cd27bb37b465a87c60cbf7d68e0dc
Source dataset
uspto-grants-1985_04
Patent number
US04511735

Reaction notes

Loading…