HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1982215Generated: November 2, 2026
Nitromethane → 3,4-Dibenzyloxy-beta-nitrostyrene
https://huagongshe.com/reaction/1982215
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Nitromethane | HCID 6375 | — |
| Reactant | 3,4-Bis(benzyloxy)benzaldehyde | HCID 79526 | — |
| Reactant | Ammonium Acetate | HCID 517165 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | 3,4-Dibenzyloxy-beta-nitrostyrene | HCID 563776 | 74.5% |
Reaction Steps
A mixture of 79.5 g (1.25 mol) of 3,4-dibenzyloxybenzaldehyde (11) (available from Aldrich Chemical Co.), 47 g CH3CO2NH4, 47 g CH3NO2, and 400 ml CH3CO2H is refluxed for two hours. The mixture is cooled to 23° C. to precipitate the product. The yellow solid is isolated by filtration, washed with ethanol, and air dried. Recrystallization from CH3CO2H--C2H5OH gives 67.2 g (74.5%) of (12): mp 118°-119° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US04595765 |
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| Source dataset | uspto-grants-1986_06 |
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| ORD ID | ord-90e2e6929ce84f9aaf07dc2ab3990ef2 |
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| Source note | uspto-grants-1986_06 |
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