HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sulfuryl chloride → 1-(Chloromethoxy)-3-(trifluoromethyl)benzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sulfuryl chloride | HCID 24648 | — |
| Reactant | HCID 13097729 | HCID 13097729 | — |
| Product | 1-(Chloromethoxy)-3-(trifluoromethyl)benzene | HCID 13097733 | 89% |
Reaction Steps
The title compound was prepared as described in Preparation 3 (b) by reaction of 1-(4-chlorophenylthio) methoxy-3-trifluoromethyl-benzene and sulfuryl chloride; yield 89%, b.p. 88°-90° C./15 mmHg. 1H NMR (CDCl3): δ 5.82 (CH2), 7.26 (Ph). MS [70 eV; m/z (% rel.int.)]: 212/210 (10/34,M); 191 (12), 175 (100), 145 (76), 133 (13), 127 (19), 114 (11), 113 (11).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04596870 |
| Source dataset | uspto-grants-1986_06 |
| ORD ID | ord-e3ddcd3579d24cd199f4f8ba65944310 |
| Source note | uspto-grants-1986_06 |