HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-(4-Cyanomethylbenzyl)phenyl 2,3,4,6-tetra-O-acetyl-beta-D-glucopyranoside → 2-(4-Cyanomethylbenzyl)phenyl 2,3,4,6-tetra-O-acetyl-beta-D-glucopyranoside
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-(4-Cyanomethylbenzyl)phenyl 2,3,4,6-tetra-O-acetyl-beta-D-glucopyranoside | HCID 12085617 | — |
| Reactant | 4-(2-Hydroxybenzyl)phenylacetonitrile | HCID 21909275 | — |
| Product | 2-(4-Cyanomethylbenzyl)phenyl 2,3,4,6-tetra-O-acetyl-beta-D-glucopyranoside | HCID 12085617 | — |
| Product | 2-(4-Cyanomethylbenzyl)Phenyl beta-D-glucopyranoside | HCID 68875018 | — |
Reaction Steps
2-(4-Cyanomethylbenzyl)phenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside was prepared in a similar manner to that described in Reference Example 25 using 4-(2-hydroxybenzyl)phenylacetonitrile instead of methyl 4-(2-hydroxybenzyl)benzoate. Then, the title compound was prepared in a similar manner to that described in Reference Example 50 using 2-(4-cyanomethylbenzyl)phenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside instead of 2-(4-methoxycarbonylbenzyl)-phenyl 2,3,4,6-tetra-O-acetyl-BD-glucopyranoside.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07541341B2 |
| Source dataset | uspto-grants-2009_06 |
| ORD ID | ord-c81f7c4a60364e9791bf2ca55a2d46aa |
| Source note | uspto-grants-2009_06 |