Allyltributylstannane → HCID 10218034, compound

HRID 1985271Notes

Reaction equation

[CH3:1][O:2][C:3](=[O:36])[C:4]([O:7][C:8]1[CH:13]=[CH:12][C:11]([CH2:14][CH2:15][CH2:16][CH:17]2[CH2:21][N:20]([CH2:22][C:23]3[CH:28]=[CH:27][C:26]([C:29]([CH3:32])([CH3:31])[CH3:30])=[CH:25][CH:24]=3)[C:19](=[O:33])[N:18]2[CH3:34])=[CH:10][C:9]=1I)([CH3:6])[CH3:5].[CH2:37]([Sn](CCCC)(CCCC)CCCC)[CH:38]=[CH2:39]>>[CH3:1][O:2][C:3](=[O:36])[C:4]([O:7][C:8]1[CH:13]=[CH:12][C:11]([CH2:14][CH2:15][CH2:16][CH:17]2[CH2:21][N:20]([CH2:22][C:23]3[CH:28]=[CH:27][C:26]([C:29]([CH3:32])([CH3:31])[CH3:30])=[CH:25][CH:24]=3)[C:19](=[O:33])[N:18]2[CH3:34])=[CH:10][C:9]=1[CH2:39][CH:38]=[CH2:37])([CH3:6])[CH3:5]

Participants

Reactant 2

HCID 90628Allyltributylstannane

HCID 68869384HCID 68869384, compound

Product 1

HCID 10218034HCID 10218034, compound

Procedure

The titled compound was prepared using 2-(4-{3-[1-(4-tert-Butyl-benzyl)-3-methyl-2-oxo-imidazolidin-4-yl]-propyl}-2-iodo-phenoxy)-2-methyl-propionic acid methyl ester (0.200 g, 0.330 mmole) and allyl tributyltin (0.218, 0.659 mmole) to produce a colorless oil (0.102 g, 59%). Mass [EI+] 521 (M+H)+.

Sources & evidence

ORD record: ord-a3122b487b694cc8af8ab62e8598ded2
Source dataset: uspto-grants-2009_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07544812B2

Reaction notes

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