Hydrazine hydrate (1:1) → (1SR,8RS)-5-(2,2-Dimethyl-propyl)-3,4-diaza-tricyclo[6.2.1.02,7]undeca-2,4,6,-triene

HRID 1985601Notes

Reaction equation

HRID 1985601 reaction equation
[CH:1]12[CH2:7][CH:4]([CH2:5][CH2:6]1)[C:3](=O)[C:2]2=O.COP([CH2:16][C:17](=O)[CH2:18][C:19]([CH3:22])([CH3:21])[CH3:20])(=O)OC.O.[NH2:25][NH2:26]>>[CH3:20][C:19]([CH3:22])([CH3:21])[CH2:18][C:17]1[CH:16]=[C:3]2[C:2]([CH:1]3[CH2:7][CH:4]2[CH2:5][CH2:6]3)=[N:26][N:25]=1

Participants

4

Reactant 3

HCID 24654Hydrazine hydrate (1:1)HCID 138696Bicyclo(2.2.1)heptane-2,3-dioneHCID 25112585(4,4-Dimethyl-2-oxo-pentyl)-phosphonic acid dimethyl ester

Product 1

HCID 69059352(1SR,8RS)-5-(2,2-Dimethyl-propyl)-3,4-diaza-tricyclo[6.2.1.02,7]undeca-2,4,6,-triene

Procedure

light-yellow solid. MS (ESI): 217.2 (MH+). Prepared from bicyclo[2.2.1]heptan-2,3-dione, (4,4-dimethyl-2-oxo-pentyl)-phosphonic acid dimethyl ester, hydrazine monohydrate.

Sources & evidence

ORD record
ord-c576137db1a9438987e20392dca4a2c0
Source dataset
uspto-grants-2009_06
Patent number
US07547697B2

Reaction notes

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