Hydrazine hydrate (1:1) → (1SR,8RS)-5-(2,2-Dimethyl-propyl)-11,11-dimethyl-3,4-diaza-tricyclo[6.2. 1.02,7]undeca-2,4,6-triene

HRID 1985615Notes

Reaction equation

HRID 1985615 reaction equation
[CH3:1][C:2]1([CH3:11])[CH:6]2[CH2:7][CH2:8][CH:3]1[C:4](=O)[C:5]2=O.COP([CH2:18][C:19](=O)[CH2:20][C:21]([CH3:24])([CH3:23])[CH3:22])(=O)OC.O.[NH2:27][NH2:28]>>[CH3:22][C:21]([CH3:24])([CH3:23])[CH2:20][C:19]1[CH:18]=[C:5]2[C:4]([CH:3]3[C:2]([CH3:11])([CH3:1])[CH:6]2[CH2:7][CH2:8]3)=[N:28][N:27]=1

Participants

4

Reactant 3

HCID 24654Hydrazine hydrate (1:1)HCID 38024027,7-Dimethylbicyclo[2.2.1]heptane-2,3-dioneHCID 25112585(4,4-Dimethyl-2-oxo-pentyl)-phosphonic acid dimethyl ester

Product 1

HCID 69065998(1SR,8RS)-5-(2,2-Dimethyl-propyl)-11,11-dimethyl-3,4-diaza-tricyclo[6.2. 1.02,7]undeca-2,4,6-triene

Procedure

light yellow solid. MS (ESI): 245.2 (MH+). Prepared from 7,7-dimethyl-bicyclo[2.2.1]heptane-2,3-dione, (4,4-dimethyl-2-oxo-pentyl)-phosphonic acid dimethyl ester, hydrazine monohydrate.

Sources & evidence

ORD record
ord-726c7e168efb46f6ae26f767541099f4
Source dataset
uspto-grants-2009_06
Patent number
US07547697B2

Reaction notes

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