Hydrazine hydrate (1:1) → (1SR,8RS)-5-(2,2-Dimethyl-propyl)-6,11,11-trimethyl-3,4-diaza-tricyclo[6.2.1.02,7]undeca-2,4,6-triene

HRID 1985616Notes

Reaction equation

HRID 1985616 reaction equation
[CH3:1][C:2]1([CH3:11])[CH:6]2[CH2:7][CH2:8][CH:3]1[C:4](=O)[C:5]2=O.C(OP([CH:20]([CH3:28])[C:21](=O)[CH2:22][C:23]([CH3:26])([CH3:25])[CH3:24])(=O)OCC)C.O.[NH2:30][NH2:31]>>[CH3:24][C:23]([CH3:26])([CH3:25])[CH2:22][C:21]1[C:20]([CH3:28])=[C:5]2[C:4]([CH:3]3[C:2]([CH3:11])([CH3:1])[CH:6]2[CH2:7][CH2:8]3)=[N:31][N:30]=1

Participants

4

Reactant 3

HCID 24654Hydrazine hydrate (1:1)HCID 38024027,7-Dimethylbicyclo[2.2.1]heptane-2,3-dioneHCID 86617458(1,4,4-Trimethyl-2-oxo-pentyl)-phosphonic acid diethyl ester

Product 1

HCID 69065199(1SR,8RS)-5-(2,2-Dimethyl-propyl)-6,11,11-trimethyl-3,4-diaza-tricyclo[6.2.1.02,7]undeca-2,4,6-triene

Procedure

yellow solid. MS (ESI): 259.3 (MH+). Prepared from 7,7-dimethyl-bicyclo[2.2.l]heptane-2,3-dione, (1,4,4-trimethyl-2-oxo-pentyl)-phosphonic acid diethyl ester, hydrazine monohydrate.

Sources & evidence

ORD record
ord-c619ec1bd2ea4ae48f79ed9fcebaeace
Source dataset
uspto-grants-2009_06
Patent number
US07547697B2

Reaction notes

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