HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diethyl Carbonate → Ethyl 3-(2,4-dichlorophenyl)-3-oxopropanoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diethyl Carbonate | HCID 7766 | — |
| Reactant | 2',4'-Dichloroacetophenone | HCID 16693 | — |
| Reactant | Sodium hydride | HCID 24758 | — |
| Product | Ethyl 3-(2,4-dichlorophenyl)-3-oxopropanoate | HCID 542007 | — |
Reaction Steps
Synthesis of Intermediate 1a was done by standard procedure starting from 2,4-dichloroacetophenone, diethylcarbonate (25 eq) and NaH (2 eq) at 80° C. for 60 minutes.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07547679B2 |
| Source dataset | uspto-grants-2009_06 |
| ORD ID | ord-ce0bdbce82ca47e0984ad2ce2455a08f |
| Source note | uspto-grants-2009_06 |