Ethyl (4-mercapto-2-methylphenoxy)acetate → 2,5-Dimethyl-4-mercaptophenoxy-acetic acid ethyl ester

HRID 1991165Notes

Reaction equation

HRID 1991165 reaction equation
C(OC(=O)COC1C=CC(S)=CC=1C)C.[CH2:16]([O:18][C:19](=[O:34])[CH2:20][O:21][C:22]1[CH:27]=[C:26]([CH3:28])[C:25]([S:29](Cl)(=O)=O)=[CH:24][C:23]=1[CH3:33])[CH3:17]>>[CH2:16]([O:18][C:19](=[O:34])[CH2:20][O:21][C:22]1[CH:27]=[C:26]([CH3:28])[C:25]([SH:29])=[CH:24][C:23]=1[CH3:33])[CH3:17]

Participants

3

Reactant 2

HCID 16641178Ethyl (4-mercapto-2-methylphenoxy)acetateHCID 20768123Ethyl [4-(chlorosulfonyl)-2,5-dimethylphenoxy]acetate

Product 1

HCID 207681072,5-Dimethyl-4-mercaptophenoxy-acetic acid ethyl ester

Procedure

The title compound was prepared according to the method described for preparing compound 10.3, using compound 21.2 as the starting material. 1H NMR (300 MHz) (CDCl3) δ 7.11 (1H, s); 6.54 (1H, s); 4.59 (2H, s); 4.26 (2H, q, J=7.2 Hz); 3.10 (1H, s); 2.29 (3H, s); 2.21 (3H, s); 1.30 (3H, t, J=7.2 Hz).

Sources & evidence

ORD record
ord-57ed70ed97864bb5bc993d509dbdcdb7
Source dataset
uspto-grants-2010_01
Patent number
US07645779B2

Reaction notes

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