HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sulfur → 2-Fluoro-3'-methyl-1,1'-biphenyl
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sulfur | HCID 5362487 | — |
| Reactant | 2'-Fluoro-5-methyl-1,2,3,6-tetrahydro[1,1'-biphenyl]-3-ol | HCID 12853040 | — |
| Product | 2-Fluoro-3'-methyl-1,1'-biphenyl | HCID 12853041 | — |
Reaction Steps
A mixture of 5-(2-fluorophenyl)-3-methyl-2-cyclohexen-1-ol (16.6 g, 0.08 mole) and sulfur (7.8 g, 0.24 mole) was heated at 180°-230° for 7.5 hours. The reaction mixture then stood at room temperature for approximately 60 hours before it was distilled under reduced pressure to give 2'-fluoro-3-methyl[1,1'-biphenyl].
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04402973 |
| Source dataset | uspto-grants-1983_09 |
| ORD ID | ord-12efdd4a6ae9429d8a0a0c5b9c27be05 |
| Source note | uspto-grants-1983_09 |