HRID1995423

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID6641

Dicumyl peroxide

C18H22O2

HCID556607

未命名化合物

$结构：CN1C(C)(C)CC(/C(C(=O)[O-])=C(\C(=O)[O-])C2CC(C)(C)N(C)C(C)(C)C2)CC1(C)C$

HCID86739024

未命名化合物

PRODUCTS

生成物

$结构：CN1C(C)(C)CC(/C(C(=O)[O-])=C(\C(=O)[O-])C2CC(C)(C)N(C)C(C)(C)C2)CC1(C)C.COC(=O)C1C=CCCC1C(=O)OC$

HCID86739025

未命名化合物

CONDITIONS

反应条件

温度: 150 °C

PROCEDURE

实验过程

Dimethyl tetrahydrophthalate 0.8 g (1/300 mole), bis(1,2,2,6,6-pentamethyl-4-piperidyl)fumarate 2.1 g (1/200 mole) and 0.029 g of dicumyl peroxide were heated and stirred at 150° C. for five hours, and then cooled to obtain a pale yellow solid.

WORKUP

后处理

temperaturecooled
customto obtain a pale yellow solid

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-af7ea6c7bc3644c48de2840ef0dd35cc
来源数据集: uspto-grants-1983_09
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04404301
来源说明: uspto-grants-1983_09

反应 SMILES

[C:1]([O:13][CH3:14])(=[O:12])[CH:2]1[CH:11]=[CH:10][CH2:9][CH2:8][CH:3]1[C:4]([O:6][CH3:7])=[O:5].[CH3:15][N:16]1[C:21]([CH3:23])([CH3:22])[CH2:20][CH:19](/[C:24](/[C:40]([O-:42])=[O:41])=[C:25](/[CH:29]2[CH2:34][C:33]([CH3:36])([CH3:35])[N:32]([CH3:37])[C:31]([CH3:39])([CH3:38])[CH2:30]2)\[C:26]([O-:28])=[O:27])[CH2:18][C:17]1([CH3:44])[CH3:43].C(OOC(C1C=CC=CC=1)(C)C)(C1C=CC=CC=1)(C)C>>[C:4]([O:6][CH3:7])(=[O:5])[CH:3]1[CH:8]=[CH:9][CH2:10][CH2:11][CH:2]1[C:1]([O:13][CH3:14])=[O:12].[CH3:37][N:32]1[C:33]([CH3:35])([CH3:36])[CH2:34][CH:29](/[C:25](/[C:26]([O-:28])=[O:27])=[C:24](/[CH:19]2[CH2:20][C:21]([CH3:22])([CH3:23])[N:16]([CH3:15])[C:17]([CH3:44])([CH3:43])[CH2:18]2)\[C:40]([O-:42])=[O:41])[CH2:30][C:31]1([CH3:39])[CH3:38]