2(3H)-Benzoxazolone → HCID 18006573, compound

HRID 1995428Notes

Reaction equation

HRID 1995428 reaction equation
[CH:1]1[CH:2]=[CH:3][C:4]2[O:10][C:8](=[O:9])[NH:7][C:5]=2[CH:6]=1.[CH2:11]([NH:13][CH2:14][CH3:15])[CH3:12]>>[OH:10][C:4]1[CH:3]=[CH:2][CH:1]=[CH:6][C:5]=1[NH:7][C:8]([N:13]([CH2:14][CH3:15])[CH2:11][CH3:12])=[O:9]

Participants

3

Reactant 2

HCID 60432(3H)-BenzoxazoloneHCID 8021Diethylamine

Product 1

HCID 18006573HCID 18006573, compound

Procedure

Benzoxazolinone (1 mole) was stirred with 2 moles of diethylamine (dissolved in industrial alcohol) at 50° C. for 48 hours, then the alcohol and excess of diethylamine were distilled off under reduced pressure at below 60° C. The residue was taken up in acetone, the desired product was precipitated by adding water and then it was filtered off and dried under reduced pressure at 80° C.

Workup

  1. distillationthe alcohol and excess of diethylamine were distilled off under reduced pressure at below 60° C
  2. customthe desired product was precipitated
  3. additionby adding water
  4. filtrationit was filtered off
  5. customdried under reduced pressure at 80° C.

Sources & evidence

ORD record
ord-c2a09f7a36114890a5026f255dbe89ec
Source dataset
uspto-grants-1983_09
Patent number
US04404356

Reaction notes

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