Dimethylamine → HCID 14289569, compound

HRID 1995432Notes

Reaction equation

HRID 1995432 reaction equation
[Br:1][C:2]1[CH:11]=[CH:10][C:5]2[NH:6][C:7](=[O:9])[O:8][C:4]=2[CH:3]=1.[CH3:12][NH:13][CH3:14]>CO>[Br:1][C:2]1[CH:11]=[CH:10][C:5]([NH:6][C:7]([N:13]([CH3:14])[CH3:12])=[O:9])=[C:4]([OH:8])[CH:3]=1

Participants

4

Reactant 2

HCID 674DimethylamineHCID 298596-Bromo-2(3H)-benzoxazolone

Product 1

HCID 14289569HCID 14289569, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

6-Bromobenzoxazolinone (35.1 g) was stirred with 55 ml of a 38% solution of dimethylamine in methanol at 60° C. for 21/2 hours. The mixture was cooled and filtered, and the precipitate was washed with cold methanol to give the desired urea (17.9 g), m.pt. 178° C. (decomp.).

Workup

  1. temperatureThe mixture was cooled
  2. filtrationfiltered
  3. washthe precipitate was washed with cold methanol

Sources & evidence

ORD record
ord-7ae1f060b38a4220b6f46784da137fa3
Source dataset
uspto-grants-1983_09
Patent number
US04404356

Reaction notes

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