HuagongsheHuagongshe Chemistry Print Report · For research reference only
2,4-Dichlorophenol → 2-(2,4-dichlorophenoxy)-1-phenylethanone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2,4-Dichlorophenol | HCID 8449 | — |
| Reactant | Ethanone, 1-(2-chlorophenyl)- | HCID 72864 | — |
| Reactant | Sodium | HCID 5360545 | — |
| Reactant | Potassium | HCID 5462222 | — |
| Catalyst | Copper | HCID 23978 | — |
| Product | 2-(2,4-dichlorophenoxy)-1-phenylethanone | HCID 2982023 | — |
Reaction Steps
Hitherto this compound has been prepared by reacting o-chloroacetophenone with the sodium or potassium salt of 2,4-dichlorophenol at a temperature of at least 120° C. in the presence of a copper catalyst to produce 2-(2,4-dichlorophenoxy)acetophenone. This is then reacted with sulphur and morpholine to afford a thioacetmorpholide which is thereafter hydrolysed.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04404396 |
| Source dataset | uspto-grants-1983_09 |
| ORD ID | ord-3d4b214e08dd4721ba8d74e862824c8a |
| Source note | uspto-grants-1983_09 |