HuagongsheHuagongshe Chemistry Print Report · For research reference only
Glycidol → 3-(4-Hydroxy-2,2,6,6-tetramethylpiperidin-1-yl)propane-1,2-diol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Glycidol | HCID 11164 | — |
| Reactant | 4-Hydroxy-2,2,6,6-tetramethylpiperidine | HCID 75471 | — |
| Solvent | Isopropanol | HCID 3776 | — |
| Product | 3-(4-Hydroxy-2,2,6,6-tetramethylpiperidin-1-yl)propane-1,2-diol | HCID 20487804 | — |
Reaction Steps
2,2,6,6-Tetramethyl-4-piperidinol 15.7 g and glycidol 7.8 g were dissolved in 50 ml of isopropanol and refluxed for five hours. Isopropanol was distilled off and the residue was recrystallized from n-hexane. A white powder, 21.3 g m.p. 97° to 99° C., was obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04405737 |
| Source dataset | uspto-grants-1983_09 |
| ORD ID | ord-b6b35d2159834948b0534c6b9ac190f1 |
| Source note | uspto-grants-1983_09 |