HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methanol → HCID 66881002, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methanol | HCID 887 | — |
| Reactant | 2-Methylbenzenesulfonamide | HCID 6924 | — |
| Reactant | Methyl 3,4-bis(bromomethyl)benzoate | HCID 2736819 | — |
| Reactant | Sodium | HCID 5360545 | — |
| Product | HCID 66881002 | HCID 66881002 | — |
Reaction Steps
Sodium (0.60 g) is dissolved in methanol (100 mL) and toluene sulfonamide (4.25 g) is added portion wise. After 30 min at ambient temperature 3,4-bis-bromomethyl-benzoic acid methyl ester are added (4.00 g). After stirring overnight, the resulting solid is collected, washed with methanol and dried. 2.80 g of the title compound are obtained with MP=164-166° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08575193B2 |
| Source dataset | uspto-grants-2013_11 |
| ORD ID | ord-162c004f76cb4eeabf8982683195f918 |
| Source note | uspto-grants-2013_11 |